Champions Manchester City begin their title defence away to West Ham United, while last-season’s runners-up Liverpool visit newly-promoted Fulham.
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The most prestigious football tournament on the continent will kick off on January 9, 2022 and end on February 6, 2022.
Inter Milan, last season’s runners-up, will visit promoted Benevento in their opening fixture.
They will take on FC Barcelona in the season’s first Classico just over one month later, according to Monday’s draw for the 2020/2021 season’s fixtures.
Next season’s competition is scheduled to begin on September 1 only a month after the 2020 final with the showpiece match at Wembley set to take place on May 15, 2021.
In Friday’s draw, Barca or Napoli were paired with Chelsea or Bayern in the last eight, with the matches to take place in Portugal next month.
United host Chelsea in the English Premier League on Sunday to kick off a run of four home games in their next five matches.