The 44-year-old, who stepped down from his role at Sevilla having guided them to an unprecedented third consecutive Europa League success, has signed a two-year deal at the Parc des Princes
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Liverpool took the lead in the 35th minute when Daniel Sturridge found the far corner, but Kevin Gameiro levelled 17 seconds after the restart, before Coke netted a double as Sevilla won the competition for a record fifth time
Jurgen Klopp’s side earned a place in the final four after coming from 3-1 down to beat Dortmund 4-3 on the night and 5-4 on aggregate
City, already through to the last 16, knew that victory would see them top the group if Juventus failed to beat Sevilla
The visitors started the match positively, and took the lead on eight minutes
Barca applied more pressure in the 10th minute as Sergio Busquets headed the ball down for Munir El Haddadi to strike inside the box, but the winger blazed his effort over the bar
The showpiece, being played between two Spanish teams for the second consecutive year, was lit up by a free kick masterclass in the first half, with Ever Banega giving his side a perfect start by curling his set piece into the top corner after just three minutes
The holders made a bright start to the match, but found themselves trailing the Ukrainian outfit – appearing in their first European final – inside 10 minutes when Nikola Kalinic, preferred to semi-final hero Yevhen Seleznyov, nodded home Matheus Nascimento’s lofted cross following a quick counter-attack