Enyimba had the best of the home advantage, beating Libyan visitors Al Ittihad 2-0.
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Friday Ubong scored a late winner as he unleashed a powerful shot four minutes from the end of regulation time to hand the Promise Keepers a crucial advantage going into the second leg next week.
Serbian football international Aleksandar Prijovic was sentenced to three months of home detention for violating lockdown rules in connection with the novel coronavirus pandemic, local media reported on Sunday.
Two goals very early in the game gave the former African champions a valuable result, which will serve them in good stead in the second leg match on March 18