The left back – a five-time European champion – was firmly behind Ferland Mendy in Real Madrid’s pecking order last term.
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As ever, this game could play a key role in determining the order of finishers at the top of La Liga, with both Los Blancos and the Blaugrana hungry to challenge Atletico Madrid in what has become a three-horse race for the title.
The French left-back’s strike in Bergamo came four minutes from time in a last 16 first leg game, which the hosts played a man down for over 70 minutes as Zinedine Zidane’s side hold the advantage heading into the second leg in Madrid on March 16.
The fee is believed to be in the region of 50 million euros (£44.5 million) and the 24-year-old will become the sixth new arrival at the Bernabeu over the summer following Eden Hazard, Luka Jovic, Eder Militao, Rodrygo and Andriy Lunin