This was after knocking out Atletico Madrid in a thrilling tie on Tuesday to set up a meeting with the French side they played in the group stage.
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Atletico made a strong start with Griezmann opening the scoring in the sixth minute with a low shot from the edge of the box.
Atletico Madrid battled back twice to draw 2-2 at Celtic in a thrilling Champions League Group E clash on Wednesday in which the Spanish side played the last few minutes with 10 men.
Atletico Madrid striker, Memphis Depay, scored with a stunning long-range strike in the second half to help secure a 3-1 home win over promoted Granada in their LaLiga opener on Monday.
The Spanish clubs had decided to appeal the penalties placed upon them by the world governing body, having breached rules regarding the transfer of non-Spanish players under the age of 18.
The first encounter in Eindhoven ended goalless and saw the hosts lose Gaston Pereiro to a second yellow card midway through the second half, setting up a finely poised clash in Madrid
Karim Benzema’s early opener was cancelled out by Luciano Vietto on 84 minutes at the Vicente Calderon as Atletico – who missed a first-half penalty through Antoine Griezmann – held their bitter neighbours to a draw last night
The only negative aspect for Atletico were the injuries to Diego Costa and Arda Turan who were substituted off in the first half
Mourinho, set to leave Real at the end of the season and rejoin Chelsea, was the first to get his marching orders after barking at the officials